| Name | Event | Year & Venue of Olympics |
|---|---|---|
| C. K. Lekshmanan | 110 m Hurdles | 1924-Paris |
| Ivan Jacob | 400m | 1952-Helsinki |
| Suresh Babu | High Jump | 1972-Munich |
| T. C. Yohannan | Long Jump | 1976-Montreal |
| P. T. Usha | 100m, 200m | 1980-Moscow |
| P. T. Usha | 400m Hurdles | 1984-Los Angeles, 1988-Seoul |
| Shiny Wilson | 800m | 1984-Los Angeles, 1988-Seoul, 1992-Barcelona, 1996-Atlanta |
| M. D. Valsamma | 4x400m | 1984-Los Angeles |
| Mercy Mathew Kuttan | 400m | 1988-Seoul |
| P. T. Usha | 4x400m (Reserve) | 1996-Atlanta |
| K. M. Beenamol | 4x400m | 1996-Atlanta, 2004-Athens |
| K. M. Beenamol | 400m | 2000-Sydney |
| K. M. Binu | 400m | 2004-Athens |
| Anju Bobby George | Long Jump | 2004-Athens, 2008-Beijing |
| Chitra K. Soman | 4x400m | 2004-Athens, 2008-Beijing |
| Preeja Sreedharan | 10000m | 2008-Beijing |
| Sini Jose | 4x400m | 2008-Beijing |
| Renjith Maheswary | Triple Jump | 2008-Beijing |
